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GHS Classification and EU Safty & Risk Phrases

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发表于 2023-11-8 02:32:42 | 显示全部楼层 |阅读模式

GHS, Globally Harmonized System of Classification and Labeling of Chemicals, was developed by the United Nations as a way to bring into agreement the chemical regulations and standards of different countries. GHS includes criteria for the classification of health, physical and environmental hazards, as well as specifying what information should be included on labels of hazardous chemicals as well as safety data sheets. Ref: UNECE GHS (Rev.6) (2015)

Hazard Class Pictograms
Exploding Bomb
Explosives(爆炸物)
GHS01
Flame
Flammables(易燃物)
GHS02
Flame Over Circle
Oxidizers(氧化物)
GHS03
Gas Cylinder
Compressed Gases(高压气体)
GHS04
Corrosion
Corrosives(腐蚀性)
GHS05
Skull and Crossbones
Acute Toxicity(有毒物质)
GHS06
Exclamation Mark
Irritant(有害)
GHS07
Health Hazard(健康危害)
GHS08
Environment(环境危害)
GHS09

EU Hazard Pictograms and Codes
C
Corrosive
腐蚀性
E
Explosive
爆炸品
F
Extremely Flammable
高度易燃品
F+
Extremely Extremely Flammable
极度易燃品
N
Dangerous for the environment
对环境有害
O
Oxidizing
氧化剂
T
Toxic
有毒
T+
Very Toxic
剧毒品
Xi
Irritant
刺激物
Xn
Toxic
有害

ISO 7010
B
Biohazard
生物危害
R
Radioactive
放射性的

GHS Hazard Statements
CodeHazard StatementsHazard ClassCategoryPictogramSignal Word   Precautionary Statements P-Codes
PreventionResponseStorageDisposal
H200
Unstable Explosive
Explosives
Unstable Explosive
Danger
P201, P202, P281
P372, P373, P380
P401
P501
H201
Explosive; mass explosion hazard
Div 1.1
Danger
P210, P230, P240, P250, P280
P370+P380, P372, P373
P401
P501
H202
Explosive; severe projection hazard
Div 1.2
Danger
P210, P230, P240, P250, P280
P370+P380, P372, P373
P401
P501
H203
Explosive; fire, blast or projection hazard
Div 1.3
Danger
P210, P230, P240, P250, P280
P370+P380, P372, P373
P401
P501
H204
Fire or projection hazard
Div 1.4
Warning
P210, P240, P250, P280
P370+P380, P372, P373, P374
P401
P501
H205
May mass explode in fire
Div 1.5
None
Danger
P210, P230, P240, P250, P280
P370+P380, P372, P373
P401
P501
Div 1.6*
H220
Extremely flammable gas
Flammable gases
Category 1
Danger
P210
P377, P381
P403
H221
Flammable gas
Category 2
None
Warning
P210
P377, P381
P403
H222
Extremely flammable aerosol
Flammable aerosols
Category 1
Danger
P210, P211, P251
P410+P412
H223
Flammable aerosol
Category 2
Warning
P210, P211, P251
P410+P412
H224
Extremely flammable liquid and vapor
Flammable liquids
Category 1
Danger
P210, P233, P240, P241, P242, P243, P280
P303+P361+P353, P370+P378
P403+P235
P501
H225
Highly Flammable liquid and vapor
Category 2
Danger
P210, P233, P240, P241, P242, P243, P280
P303+P361+P353, P370+P378
P403+P235
P501
H226
Flammable liquid and vapor
Category 3
Warning
P210, P233, P240, P241, P242, P243, P280
P303+P361+P353, P370+P378
P403+P235
P501
H227
Combustible liquid
Category 4
None
Warning
P210, P280
P370+P378
P403+P235
P501
H228
Flammable solid
Flammable solids
Category 1
Danger
P210, P240, P241, P280
P370+P378
H228
Flammable solid
Category 2
Warning
P210, P240, P241, P280
P370+P378
H240
Heating may cause an explosion
Self-reactive substances and mixtures; and Organic peroxides
Type A
Danger
P210, P220, P234, P280
P370+P378, P370+P380+P375
P403+P235, P411, P420
P501
H241
Heating may cause a fire or explosion
Type B
Danger
P210, P220, P234, P280
P370+P378, P370+P380+P375
P403+P235, P411, P420
P501
H242
Heating may cause a fire
Type C, D,
Danger
P210, P220, P234, P280
P370+P378
P403+P235, P411, P420
P501
H242
Heating may cause a fire
Type E, F, G
Warning
P210, P220, P234, P280
P370+P378
P403+P235, P411, P420
P501
H250
Catches fire spontaneously if exposed to air
Pyrophoric liquids; Pyrophoric solids
Category 1
Danger
P210, P222, P280
P302+P334, P370+P378
P422
H251
Self-heating; may catch fire
Self-heating substances and mixtures
Category 1
Danger
P235+P410, P280
P407, P413, P420
H252
Self-heating in large quantities; may catch fire
Category 2
Warning
P235+P410, P280
P407, P413, P420
H260
In contact with water releases flammable gases which may ignite spontaneously
Substances And Mixtures Which, In Contact With Water, Emit Flammable Gases
Category 1
Danger
P223, P231+P232, P280
P335+P334, P370+P378
P402+P404
P501
H261
In contact with water releases flammable gas
Category 2
Danger
P223, P231+P232, P280
P335+P334, P370+P378
P402+P404
P501
H261
In contact with water releases flammable gas
Category 3
Warning
P231+P232, P280
P370+P378
P402+P404
P501
H270
May cause or intensify fire; oxidizer
Oxidizing gases
Category 1
Danger
P220, P244
P370+P376
P403
H271
May cause fire or explosion; strong Oxidizer
Oxidizing liquids; Oxidizing solids
Category 1
Danger
P210, P220, P221, P280, P283
P306+P360, P371+P380+P375, P370+P378
P501
H272
May intensify fire; oxidizer
Category 2
Danger
P210, P220, P221, P280
P370+P378
P501
H272
May intensify fire; oxidizer
Category 3
Warning
P210, P220, P221, P280
P370+P378
P501
H280
Contains gas under pressure; may explode if heated
Gases under pressure
Compressed gas, Liquefied gas, Dissolved gas
Warning
P410+P403
H281
Contains refrigerated gas; may cause cryogenic burns or injury
Refrigerated liquefied gas
Warning
P282
P336, P315
P403
H290
May be corrosive to metals
Corrosive to Metals
Category 1
Warning
P234
P390
P404
H300
Fatal if swallowed
Acute toxicity, oral
Category 1, 2
Danger
P264, P270
P301+P310, P321, P330
P405
P501
H301
Toxic if swallowed
Category 3
Danger
P264, P270
P301+P310, P321, P330
P405
P501
H302
Harmful if swallowed
Category 4
Warning
P264, P270
P301+P312, P330
P501
H303
May be harmful if swallowed
Category 5
None
Warning
P312
H304
May be fatal if swallowed and enters airways
Aspiration hazard
Category 1
Danger
P301+P310, P331
P405
P501
H305
May be fatal if swallowed and enters airways
Category 2
Warning
P301+P310, P331
P405
P501
H310
Fatal in contact with skin
Acute toxicity, dermal
Category 1, 2
Danger
P262, P264, P270, P280
P302+P350, P310, P322, P361, P363
P405
P501
H311
Toxic in contact with skin
Category 3
Danger
P280
P302+P352, P312, P322, P361, P363
P405
P501
H312
Harmful in contact with skin
Category 4
Warning
P280
P302+P352, P312, P322, P363
P501
H313
May be harmful in contact with skin
Category 5
None
P312
H314
Causes severe skin burns and eye damage
Skin corrosion/irritation
Category 1A, B, C
Danger
P260, P264, P280
P301+P330+P331, P303+P361+P353, P363, P304+P340, P310, P321, P305+P351+P338
P405
P501
H315
Causes skin irritation
Category 2
Warning
P264, P280
P302+P352, P321, P332+P313, P362
H316
Causes mild skin irritation
Category 3
None
Warning
P332+P313
H317
May cause an allergic skin reaction
Sensitization, Skin
Category 1
Warning
P261, P272, P280
P302+P352, P333+P313, P321, P363
P501
H318
Causes serious eye damage
Serious eye damage/eye irritation
Category 1
Danger
P280
P305+P351+P338, P310
H319
Causes serious eye irritation
Category 2A
Warning
P264, P280
P305+P351+P338, P337+P313
H320
Causes eye irritation
Category 2B
None
Warning
P264
P305+P351+P338, P337+P313
H330
Fatal if inhaled
Acute toxicity, inhalation
Category 1, 2
Danger
P260, P271, P284
P304+P340, P310, P320
P403+P233, P405
P501
H331
Toxic if inhaled
Category 3
Danger
P261, P271
P304+P340, P311, P321
P403+P233, P405
P501
H332
Harmful if inhaled
Category 4
Warning
P261, P271
P304+P340, P312, P304+P312
H333
May be harmful if inhaled
Category 5
None
Warning
P261, P271
P304+P340, P312, P304+P312
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled
Sensitization, respiratory
Category 1
Danger
P261, P285
P304+P341, P342+P311
P501
H335
May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation
Category 3
Warning
P261, P271
P304+P340, P312
P403+P233, P405
P501
H336
May cause drowsiness or dizziness
Specific target organ toxicity, single exposure; Narcotic effects
Category 3
Warning
P261, P271
P304+P340, P312
P403+P233, P405
P501
H340
May cause genetic defects
Germ cell mutagenicity
Category 1A, 1B
Danger
P201, P202, P281
P308+P313
P405
P501
H341
Suspected of causing genetic defects
Category 2
Warning
P201, P202, P281
P308+P313
P405
P501
H350
May cause cancer
Carcinogenicity
Category 1A, 1B
Danger
P201, P202, P281
P308+P313
P405
P501
H351
Suspected of causing cancer
Category 2
Warning
P201, P202, P281
P308+P313
P405
P501
H360
May damage fertility or the unborn child
Reproductive toxicity
Category 1A, 1B
Danger
P201, P202, P281
P308+P313
P405
P501
H361
Suspected of damaging fertility or the unborn child
Category 2
Warning
P201, P202, P281
P308+P313
P405
P501
H362
May cause harm to breast-fed children
Reproductive toxicity, effects on or via lactation
Additional category
None
P201, P260, P263, P264, P270
P308+P313
H370
Causes damage to organs
Specific target organ toxicity, single exposure
Category 1
Danger
P260, P264, P270
P307+P311, P321
P405
P501
H371
May cause damage to organs
Category 2
Warning
P260, P264, P270
P309+P311
P405
P501
H372
Causes damage to organs through prolonged or repeated exposure
Specific target organ toxicity, repeated exposure
Category 1
Danger
P260, P264, P270
P314
P501
H373
Causes damage to organs through prolonged or repeated exposure
Category 2
Warning
P260
P314
P501
H400
Very toxic to aquatic life
Hazardous to the aquatic environment, acute hazard
Category 1
Warning
P273
P391
P501
H401
Toxic to aquatic life
Category 2
None
P273
P501
H402
Harmful to aquatic life
Category 3
None
P273
P501
H410
Very toxic to aquatic life with long lasting effects
Hazardous to the aquatic environment, long-term hazard
Category 1
Warning
P273
P391
P501
H411
Toxic to aquatic life with long lasting effects
Category 2
P273
P391
P501
H412
Harmful to aquatic life with long lasting effects
Category 3
None
P273
P501
H413
May cause long lasting harmful effects to aquatic life
Category 4
None
P273
P501
H420
Harms public health and the environment by destroying ozone in the upper atmosphere
Hazardous to the ozone layer
Category 1
Warning
P502
* Div 1.6 - Meets transportation requirements only. For more information, see A Guide to The Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
EU Hazard Statements
EUH001Explosive when dry
EUH006Explosive with or without contact with air
EUH014Reacts violently with water
EUH018In use may form flammable/explosive vapor-air mixture
EUH019May form explosive peroxides
EUH029Contact with water liberates toxic gas
EUH031Contact with acids liberates toxic gas
EUH032Contact with acids liberates very toxic gas
EUH044Risk of explosion if heated under confinement
EUH059Hazardous to the ozone layer
EUH066Repeated exposure may cause skin dryness or cracking
EUH070Toxic by eye contact
Safe Work Australia Hazard Statements
AUH001Explosive when dry
AUH006Explosive with or without contact with air
AUH014Reacts violently with water
AUH018In use, may form flammable/explosive vapour/air mixture
AUH019May form explosive peroxides
AUH029Contact with water liberates toxic gas
AUH031Contact with acid liberates toxic gas
AUH032Contact with acid liberates very toxic gas
AUH044Risk of explosion if heated under confinement
AUH066Repeated exposure may cause skin dryness and cracking
Precautionary Statements
General Precautionary Statements
P101If medical advice is needed, have product container or label at hand.
P102Keep out of reach of children.
P103Read label before use
Prevention Precautionary Statements
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P210Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.
P211Do not spray on an open flame or other ignition source.
P212Avoid heating under confinement or reduction of the desensitized agent.
P220Keep away from clothing and other combustible materials.
P221Take any precaution to avoid mixing with combustibles/...
P222Do not allow contact with air.
P223Do not allow contact with water.
P230Keep wetted with ...
P231Handle under inert gas.
P232Protect from moisture.
P233Keep container tightly closed.
P234Keep only in original container.
P235Keep cool.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof [electrical/ventilating/lighting/.../] equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
P244Keep valves and fittings free from oil and grease.
P250Do not subject to grinding/shock/friction/...
P251Do not pierce or burn, even after use.
P260Do not breathe dust/fume/gas/mist/vapors/spray.
P261Avoid breathing dust/fume/gas/mist/vapors/spray.
P262Do not get in eyes, on skin, or on clothing.
P263Avoid contact during pregnancy/while nursing.
P264Wash ... thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P281Use personal protective equipment as required.
P282Wear cold insulating gloves/face shield/eye protection.
P283Wear fire resistant or flame retardant clothing.
P284[In case of inadequate ventilation] Wear respiratory protection.
P285In case of inadequate ventilation wear respiratory protection.
P231+P232Handle under inert gas/... Protect from moisture.
P235+P410Keep cool. Protect from sunlight.
Response Precautionary Statements
P301IF SWALLOWED:
P302IF ON SKIN:
P303IF ON SKIN (or hair):
P304IF INHALED:
P305IF IN EYES:
P306IF ON CLOTHING:
P307IF exposed:
P308IF exposed or concerned:
P309IF exposed or if you feel unwell
P310Immediately call a POISON CENTER or doctor/physician.
P311Call a POISON CENTER or doctor/...
P312Call a POISON CENTER or doctor/... if you feel unwell.
P313Get medical advice/attention.
P314Get medical advice/attention if you feel unwell.
P315Get immediate medical advice/attention.
P320Specific treatment is urgent (see ... on this label).
P321Specific treatment (see ... on this label).
P322Specific measures (see ...on this label).
P330Rinse mouth.
P331Do NOT induce vomiting.
P332IF SKIN irritation occurs:
P333If skin irritation or rash occurs:
P334Immerse in cool water [or wrap in wet bandages].
P335Brush off loose particles from skin.
P336Thaw frosted parts with lukewarm water. Do not rub affected area.
P337If eye irritation persists:
P338Remove contact lenses, if present and easy to do. Continue rinsing.
P340Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342If experiencing respiratory symptoms:
P350Gently wash with plenty of soap and water.
P351Rinse cautiously with water for several minutes.
P352Wash with plenty of water/...
P353Rinse skin with water [or shower].
P360Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361Take off immediately all contaminated clothing.
P362Take off contaminated clothing.
P363Wash contaminated clothing before reuse.
P364And wash it before reuse.[Added in 2015 version]
P370In case of fire:
P371In case of major fire and large quantities:
P372Explosion risk.
P373DO NOT fight fire when fire reaches explosives.
P374Fight fire with normal precautions from a reasonable distance.
P376Stop leak if safe to do so.
P377Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378Use ... to extinguish.
P380Evacuate area.
P381In case of leakage, eliminate all ignition sources.
P390Absorb spillage to prevent material damage.
P391Collect spillage.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER/doctor/...
P301+P312IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P334IF ON SKIN: Immerse in cool water [or wrap in wet bandages].
P302+P335+P334Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].
P302+P350IF ON SKIN: Gently wash with plenty of soap and water.
P302+P352IF ON SKIN: wash with plenty of water.
P303+P361+P353IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].
P304+P312IF INHALED: Call a POISON CENTER/doctor/... if you feel unwell.
P304+P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P304+P341IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P306+P360IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307+P311IF exposed: call a POISON CENTER or doctor/physician.
P308+P311IF exposed or concerned: Call a POISON CENTER/doctor/...
P308+P313IF exposed or concerned: Get medical advice/attention.
P309+P311IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.
P335+P334Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337+P313IF eye irritation persists: Get medical advice/attention.
P342+P311IF experiencing respiratory symptoms: Call a POISON CENTER/doctor/...
P361+P364Take off immediately all contaminated clothing and wash it before reuse.
P362+P364Take off contaminated clothing and wash it before reuse.
P370+P376in case of fire: Stop leak if safe to do so.
P370+P378In case of fire: Use ... to extinguish.
P370+P380In case of fire: Evacuate area.
P370+P380+P375In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371+P380+P375In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage Precautionary Statements
P401Store in accordance with ...
P402Store in a dry place.
P403Store in a well-ventilated place.
P404Store in a closed container.
P405Store locked up.
P406Store in corrosive resistant/... container with a resistant inner liner.
P407Maintain air gap between stacks or pallets.
P410Protect from sunlight.
P411Store at temperatures not exceeding ... °C/...°F.
P412Do not expose to temperatures exceeding 50 °C/ 122 °F.
P413Store bulk masses greater than ... kg/...lbs at temperatures not exceeding ... °C/...°F.
P420Store separately.
P422Store contents under ...
P402+P404Store in a dry place. Store in a closed container.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P403+P235Store in a well-ventilated place. Keep cool.
P410+P403Protect from sunlight. Store in a well-ventilated place.
P410+P412Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F.
P411+P235Store at temperatures not exceeding ... °C/...°F. Keep cool.
Disposal Precautionary Statements
P501Dispose of contents/container to ...
P502Refer to manufacturer or supplier for information on recovery or recycling
EU Safety Phrases
S1Keep locked up.上锁;
S1/2Keep locked up and out of reach of children.上锁保管并避免儿童触及;
S2Keep out of reach of children.避免儿童触及;
S3Keep in a cool place.保存在阴凉处;
S3/14Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer).保存在阴凉场所,远离(生产厂家指明的不兼容的物料);
S3/7Keep container tightly closed in a cool place.将容器严格密闭保存在阴凉处;
S3/7/9Keep container tightly closed in a cool, well-ventilated place.将容器严格密闭保存在阴凉、通风良好场所;
S3/9Keep in a cool, well-ventilated place.保存在阴凉、通风良好场所;
S3/9/14Keep in a cool, well-ventilated place away from ... (incompatible material to be indicated by the manufacturer)保存在阴凉、通风良好场所,远离(生产厂家指明的不兼容的物料);
S3/9/14/49Keep only in the original container in a cool, well-ventilated place away from ...保存在原始容器中,放在阴凉通风良好场所,远离(生产厂家指明的不兼容的物料);
S3/9/49Keep only in the original container in a cool, well-ventilated place.保存在原始容器中,放在阴凉、通风良好场所;
S4Keep away from living quarters.远离生活区;
S5Keep contents under ... (appropriate liquid to be specified by the manufacturer).将该物质保存在生产厂家指定的适当液体中;
S6Keep under ... (inert gas to be specified by the manufacturer).将该物质保存在生产厂家指定的惰性气体中;
S7Keep container tightly closed.保存在严格密闭容器中;
S7/47Keep container tightly closed and at a temperature not exceeding ...鳦. (to be specified by the manufacturer)保持容器严格密闭,温度不超过….°C(由生产厂家指定);
S7/8Keep container tightly closed and dry.保存在严格密闭容器中,保持干燥;
S7/9Keep container tightly closed and in a well-ventilated place保持容器严格密闭,置于通风良好的场所;
S8Keep container dry.保持容器干燥;
S9Keep container in a well-ventilated place.保持容器在通风良好的场所;
S12Do not keep the container sealed.不要将容器密封;
S13Keep away from food, drink and animal feeding stuffs.远离食品、饮料和动物饲料保存;
S14Keep away from ... (incompatible materials to be indicated by the manufacturer).远离(生产厂家指定的不相容物质)保存;
S15Keep away from heat.远离热源;
S16Keep away from sources of ignition - No smoking.远离火源,禁止吸烟;
S17Keep away from combustible material.远离可燃物料;
S18Handle and open container with care.小心搬运和开启容器;
S20When using do not eat or drink.使用时,不得进食,饮水;
S20/21When using do not eat, drink or smoke.使用时,不得进食,饮水或吸烟;
S21When using do not smoke.使用时,禁止吸烟;
S22Do not breathe dust.不要吸入粉尘;
S23Do not breathe gas/fumes/vapour/spray.不要吸入气体/烟雾/蒸汽/喷雾;
S24Avoid contact with skin.避免皮肤接触;
S24/25Avoid contact with skin and eyes。避免皮肤和眼睛接触;
S25Avoid contact with eyes.避免眼睛接触;
S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.眼睛接触后,立即用大量水冲洗并征求医生意见;
S27Take off immediately all contaminated clothing.立即脱掉全部污染的衣服;
S28After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).皮肤接触后,立即用大量...(由生产厂家指定)冲洗;
S29Do not empty into drains.不要排入下水道;
S29/56Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.不要排入下水道,在危险废物或特殊废物收集点处置该物料及其容器;
S30Never add water to this product.切勿将水加入该产品中;
S31Keep away from explosive materials.远离爆炸物质;
S33Take precautionary measures against static discharges.对静电采取预防措施;
S34Avoid shock and friction.避免冲击和摩擦;
S35This material and its container must be disposed of in a safe way.该物料及其容器必须以安全方式处置;
S36Wear suitable protective clothing.穿戴适当的防护服;
S36/37Wear suitable protective clothing and gloves.穿戴适当的防护服和手套;
S36/37/39Wear suitable protective clothing, gloves and eye/face protection.穿戴适当的防护服、手套和眼睛/面保护;
S36/39Wear suitable protective clothing and eye/face protection.穿戴适当的防护服和眼睛/面保护;
S37Wear suitable gloves.戴适当手套;
S37/39Wear suitable gloves and eye/face protection.穿戴适当的手套和眼睛/面保护;
S38In case of insufficient ventilation, wear suitable respiratory equipment.通风不良时,佩带适当的呼吸器;
S39Wear eye/face protection.戴眼睛/面孔保护装置;
S40To clean the floor and all objects contaminated by this material, use ... (to be specified by the manufacturer).使用….(由生产厂家指定)清洗地面和被这种物料污染的所有物品;
S41In case of fire and/or explosion do not breathe fumes.着火和/或爆炸时,不要吸入烟雾;
S42During fumigation/spraying wear suitable respiratory equipment.熏蒸/喷洒时,戴适当呼吸器(由生产厂家指定);
S43In case of fire, use ... (if water increases the risk, add - never use water).着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
S44If you feel unwell, seek medical advice (show the label where possible).如果你感觉不适,征求医生意见(可能时出示标签);
S45In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).发生事故时或感觉不适时,立即求医(可能时出示标签);
S46If swallowed, seek medical advice immediately and show this container or label.食入时,立即求医并出示容器/标签;
S47Keep at temperature not exceeding ... degr. C (to be specified by the manufacturer).保持温度不超过……°C(由生产厂家指定);
S47/49Keep only in the original container at temperature not exceeding ... degr. C (to be specified by the manufacturer)保存在原始容器中,温度不超过…°C(由生产厂家指定);
S48Keep wetted with ... (appropriate material to be specified by the manufacturer).用……(生产厂家指定的适当物料)保持湿润;
S49Keep only in the original container.仅保存在原始容器中;
S50Do not mix with ... (to be specified by the manufacturer).不要与……(由生产厂家指定)混合;
S51Use only in well-ventilated areas.仅在通风良好的场所使用;
S52Not recommended for interior use on large surface areas.建议不在表面积大的区域内部使用;
S53Avoid exposure - obtain special instructions before use.避免接触,使用前获得特别指示说明;
S54Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.在排放入污水处理厂前获得官方污染控制机构许可;
S55Treat using the best available techniques before discharge into drains or the aquatic environment.在排入污水道和水生环境前进行最佳技术处理;
S56Dispose of this material and its container at hazardous or special waste collection point.在危险废物或特殊废物收集点处置该物料及其容器;
S57Use appropriate containment to avoid environmental contamination.使用适当容器避免环境污染;
S58To be disposed of as hazardous waste.作为危险废物进行处置;
S59Refer to manufacturer/supplier for information on recovery/recycling.参考生产厂家/供货商提供的回收/再生利用信息;
S60This material and/or its container must be disposed of as hazardous waste.该物质及其容器必须作为危险废物处置;
S61Avoid release to the environment. Refer to special instructions/Safety data sheets.避免释放到环境中,参考特别指示/安全收据说明书;
S62If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.吞食后不要催吐:立即求医并出示该容器或标签;
S14AKeep away from acids, reducing agents and polymerisation catalysts.远离酸、还原剂、聚合催化剂保存;
S14BKeep away from organic material and metal powders.远离有机金属化合物和金属粉末保存;
S14CKeep away from water, acids and alkali.远离水、酸、碱保存;
S28AAfter contact with skin, wash immediately with plenty of water.皮肤接触后,立即用大量水冲洗;
S28BAfter contact with skin, wash immediately with plenty of water and soap.皮肤接触后,立即用大量水、肥皂冲洗;
S28CAfter contact with skin, wash immediately with a sodium borate solution.皮肤接触后,立即用大量硼酸钠溶液冲洗;
S43AIn case of fire, use dry chemical. (never use water)着火时使用干粉消防器材种类灭火(禁止用水);
S43BIn case of fire, use fire-fighting equipment on basis of sodium chloride or sodium bicarbonate (never use water).着火时使用氯化钠或碳酸氢钠类型的消防器材种类灭火(禁止用水);
S43CIn case of fire use limestone powder, sodium chloride or dry sand (never use water).着火时使用石灰粉末、氯化钠或干沙子灭火(禁止用水);
S43DIn case of fire, use sodium carbonate or dry sand (never use water).着火时使用碳酸钠或干沙子灭火(禁止用水);
S43EIn case of fire, use dry sand (never use water).着火时使用干沙灭火(禁止用水);
S43FUse water in case of Fire用水灭火;
S47AKeep at temperature not exceeding 65 degr. C.保持温度不超过65°C;
S50ADo not mix with acids.不要与酸混合;
S5AKeep contents under oil.将该物质保持在油中;
S5BKeep contents under liquids which are oxygen-free, e.g. kerosene, toluene, etc.将该物质保持在无氧液体中,如煤油、甲苯等;
S6AKeep under nitrogen.将该物质保持在氮气中;
EU Risk Phrases
R1Explosive when dry.干燥时有爆炸性;
R2Risk of explosion by shock, friction, fire or other sources of ignition.受冲击、摩擦、着火或其他引燃源有爆炸危险;
R3Extreme risk of explosion by shock, friction, fire or other sources of ignition.受冲击、摩擦、着火或其他引燃源有极高爆炸危险;
R4Forms very sensitive explosive metallic compounds.生成极敏感的爆炸性金属化合物;
R5Heating may cause an explosion.受热可能引起爆炸;
R6Explosive with or without contact with air.与空气或未与空气接触发生爆炸;
R7May cause fire.可能引起火灾;
R8Contact with combustible material may cause fire.与可燃物料接触可能引起火灾;
R9Explosive when mixed with combustible material.与可燃物料混合时发生爆炸;
R10Flammable.易燃的;
R11Highly flammable.高度易燃的;
R12Extremely flammable.极易燃的;
R14Reacts violently with water.与水猛烈反应;
R14/15Reacts violently with water, liberating highly flammable gases.与水猛烈反应,释放出极易燃气体;
R15Contact with water liberates extremely flammable gases.与水接触释放出极易燃气体;
R15/29Contact with water liberates toxic, highly flammable gas.与水接触释放出有毒的,极易燃气体;
R16Explosive when mixed with oxidizing substances.与氧化性物质混合时发生爆炸;
R17Spontaneously flammable in air.在空气中易自燃;
R18In use, may form flammable/explosive vapour-air mixture.使用中可能形成易燃/爆炸性蒸气空气混合物;
R19May form explosive peroxides.可能生成爆炸性过氧化物;
R20Harmful by inhalation.吸入有害;
R20/21Harmful by inhalation and in contact with skin.吸入和与皮肤接触是有害的;
R20/21/22Harmful by inhalation, in contact with skin and if swallowed.吸入、与皮肤接触和吞食是有害的;
R20/22Harmful by inhalation and if swallowed.吸入和吞食是有害的;
R21Harmful in contact with skin.与皮肤接触是有害的;
R21/22Harmful in contact with skin and if swallowed.与皮肤接触和吞食是有毒的;
R22Harmful if swallowed.吞食是有害的;
R23Toxic by inhalation.吸入有害;
R23/24Toxic by inhalation and in contact with skin.吸入和与皮肤接触是有毒的;
R23/24/25Toxic by inhalation, in contact with skin and if swallowed.吸入、与皮肤接触和吞食是有毒的;
R23/25Toxic by inhalation and if swallowed.吸入和吞食是有毒的;
R24Toxic in contact with skin.与皮肤接触有毒;
R24/25Toxic in contact with skin and if swallowed.与皮肤接触和吞食是有毒的;
R25Toxic if swallowed.吞食有毒;
R26Very toxic by inhalation.吸入有极高毒性;
R26/27Very toxic by inhalation and in contact with skin.吸入和与皮肤接触有极高毒性;
R26/27/28Very toxic by inhalation, in contact with skin and if swallowed.吸入、与皮肤接触和吞食有极高毒性;
R26/28Very toxic by inhalation and if swallowed.吸入和吞食有极高毒性;
R27Very toxic in contact with skin.与皮肤接触有极高毒性;
R27/28Very toxic in contact with skin and if swallowed.与皮肤接触和吞食有极高毒性;
R28Very toxic if swallowed.吞食有极高毒性;
R29Contact with water liberates toxic gas.与水接触释放出有毒气体;
R30Can become highly flammable in use.使用会变为高度易燃的;
R31Contact with acids liberates toxic gas.与酸接触释放出有毒气体;
R32Contact with acids liberates very toxic gas.与酸接触释放出极高毒性气体;
R33Danger of cumulative effects.有累积作用危险;
R34Causes burns.引起灼伤;
R35Causes severe burns.引起严重灼伤;
R36Irritating to eyes.刺激眼睛;
R36/37Irritating to eyes and respiratory system.刺激眼睛和呼吸系统;
R36/37/38Irritating to eyes, respiratory system and skin.刺激眼睛、呼吸系统和皮肤;
R36/38Irritating to eyes and skin.刺激眼睛和皮肤;
R37Irritating to respiratory system.刺激呼吸系统;
R37/38Irritating to respiratory system and skin.刺激呼吸系统和皮肤;
R38Irritating to skin.刺激皮肤;
R39Danger of very serious irreversible effects.有极严重不可逆作用危险;
R39/23Toxic : danger of very serious irreversible effects through inhalation.有毒的:经吸入有极严重不可逆作用危险;
R39/23/24Toxic : danger of very serious irreversible effects through inhalation and in contact with skin.有毒的:经吸入和与皮肤接触有极严重不可逆作用危险;
R39/23/24/25Toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.有毒的:经吸入、与皮肤接触和吞食有极严重不可逆作用危险;
R39/23/25Toxic : danger of very serious irreversible effects through inhalation and if swallowed.有毒的:经吸入和吞食有极严重不可逆作用危险;
R39/24Toxic : danger of very serious irreversible effects in contact with skin.有毒的:与皮肤接触有极严重不可逆作用危险;
R39/24/25Toxic : danger of very serious irreversible effects in contact with skin and if swallowed.有毒的:与皮肤接触和吞食有极严重不可逆作用危险;
R39/25Toxic : danger of very serious irreversible effects if swallowed.有毒的:吞食有极严重不可逆作用危险;
R39/26Very toxic : danger of very serious irreversible effects through inhalation.极高毒性:经吸入有极严重不可逆作用危险;
R39/26/27Very toxic : danger of very serious irreversible effects through inhalation and in contact with skin.极高毒性:经吸入和与皮肤接触有极严重不可逆作用危险;
R39/26/27/28Very toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.极高毒性:经吸入、与皮肤接触和吞食有极严重不可逆作用危险;
R39/26/28Very toxic : danger of very serious irreversible effects through inhalation and if swallowed.极高毒性:经吸入和吞食有极严重不可逆作用危险;
R39/27Very toxic : danger of very serious irreversible effects in contact with skin.极高毒性:与皮肤接触有极严重不可逆作用危险;
R39/27/28Very toxic : danger of very serious irreversible effects in contact with skin and if swallowed.极高毒性:与皮肤接触和吞食有极严重不可逆作用危险;
R39/28Very toxic : danger of very serious irreversible effects if swallowed.极高毒性:吞食有极严重不可逆作用危险;
R40Possible risks of irreversible effects.可能有不可逆作用的风险;
R40/20Harmful : possible risk of irreversible effects through inhalation.有害的:经吸入可能有不可逆作用的风险;
R40/20/21Harmful : possible risk of irreversible effects through inhalation and in contact with skin.有害的:经吸入和与皮肤接触可能有不可逆作用的风险;
R40/20/21/22Harmful : possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.有害的:经吸入、与皮肤接触和吞食可能有不可逆作用的风险;
R40/20/22Harmful : possible risk of irreversible effects through inhalation and if swallowed.有害的:经吸入和吞食可能有不可逆作用的风险;
R40/21Harmful : possible risk of irreversible effects in contact with skin.有害的:与皮肤接触可能有不可逆作用的风险;
R40/21/22Harmful : possible risk of irreversible effects in contact with skin and if swallowed.有害的:与皮肤接触和吞食可能有不可逆作用的风险;
R40/22Harmful : possible risk of irreversible effects if swallowed有害的:吞食可能有不可逆作用的风险;
R41Risk of serious damage to eyes.对眼睛有严重损害的风险;
R42May cause sensitization by inhalation.吸入可能引起过敏;
R42/43May cause sensitization by inhalation and skin contact.吸入和皮肤接触可能引起过敏;
R43May cause sensitization by skin contact.皮肤接触可能引起过敏;
R44Risk of explosion if heated under confinement.在封闭情况下加热有爆炸危险;
R45May cause cancer.可能致癌;
R46May cause heritable genetic damage.可能造成不可逆的遗传损害
R47May cause birth defects.可能引起出生缺陷;
R48Danger of serious damage to health by prolonged exposure.长期接触有严重损害健康的危险;
R48/20Harmful : danger of serious damage to health by prolonged exposure through inhalation.有害的:经吸入长期接触有严重损害健康的危险;
R48/20/21Harmful : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.有害的:经吸入和与皮肤长期接触有严重损害健康的危险;
R48/20/21/22Harmful : danger of serious damage to health by prolonged exposure through inh.,in contact with skin and if swallowed有害的:经吸入、皮肤和吞食长期接触有严重损害健康的危险;
R48/20/22Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.有害的:经吸入和吞食长期接触有严重损害健康的危险;
R48/21Harmful : danger of serious damage to health by prolonged exposure in contact with skin.有害的:经皮肤长期接触有严重损害健康的危险;
R48/21/22Harmful : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.有害的:经皮肤和吞食长期接触有严重损害健康的危险;
R48/22Harmful : danger of serious damage to health by prolonged exposure if swallowed.有害的:吞食长期接触有严重损害健康的危险;
R48/23Toxic : danger of serious damage to health by prolonged exposure through inhalation.有毒的:经吸入长期接触有严重损害健康的危险;
R48/23/24Toxic : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.有毒的:经吸入和与皮肤长期接触有严重损害健康的危险;
R48/23/24/25Toxic : danger of serious damage to health by prolonged exposure through inh.,in contact with skin and if swallowed有毒的:经吸入、皮肤和吞食长期接触有严重损害健康的危险;
R48/23/25Toxic : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.有毒的:经吸入和吞食长期接触有严重损害健康的危险;
R48/24Toxic : danger of serious damage to health by prolonged exposure in contact with skin.有毒的:经皮肤长期接触有严重损害健康的危险;
R48/24/25Toxic : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.有毒的:经皮肤和吞食长期接触有严重损害健康的危险;
R48/25Toxic : danger of serious damage to health by prolonged exposure if swallowed.有毒的:吞食长期接触有严重损害健康的危险;
R49May cause cancer by inhalation.吸入可能致癌;
R50Very toxic to aquatic organisms.对水生生物有极高毒性;
R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.对水生生物有极高毒性,可能在水生环境中造成长期不利影响;
R51Toxic to aquatic organisms.对水生生物是有毒的;
R51/53Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.对水生生物有毒,可能在水生环境中造成长期不利影响;
R52Harmful to aquatic organisms.对水生生物是有害的;
R52/53Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.对水生生物有害,可能在水生环境中造成长期不利影响;
R53May cause long-term adverse effects in aquatic environment.可能在水生环境中造成长期不利影响;
R54Toxic to flora.对植物群有毒;
R55Toxic to fauna.对动物群有毒;
R56Toxic to soil organisms.对土壤中生物有毒;
R57Toxic to bees.对蜜蜂有毒;
R58May cause long-term adverse effects in the environment.可能在环境中造成长期不利影响;
R59Dangerous for the ozon layer.对臭氧层有危害;
R60May impair fertility.可能损伤生育力;
R61May cause harm to the unborn child.可能对未出生婴儿造成危害;
R62Possible risk of impaired fertility.可能有损伤生育力的危险;
R63Possible risk of harm to the unborn child.可能有损害未出生婴儿的危险;
R64May cause harm to breastfed babies.可能对哺乳婴儿造成危害;
R65Harmfull may cause lung damage if swallowed有害的:吞食可能造成肺部损害;

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