Indication of Particular Risks

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R1: Explosive when dry 2: Risk of explosion by shock, friction, fire or other sources of ignition 3: Extreme risk of explosion by shock, friction, fire or other sources of ignition 4: Forms very sensitive explosive metallic compounds 5: Heating may cause an explosion 6: Explosive with or without contact with air 7: May cause fire 8: Contact with combustible material may cause fire 9: Explosive when mixed with combustible material 10: Flammable 11: Highly Flammable 12: Extremely Flammable 14: Reacts violently with water 15: Contact with water liberates extremely flammable gases 16: Explosive when mixed with oxidizing substances 17: Spontaneously flammable in air 18: In use may form flammable/explosive vapor-air mixture 19: May form explosive peroxides 20: Harmful by inhalation 21: Harmful in contact with skin 22: Harmful if swallowed 23: Toxic by inhalation 24: Toxic in contact with skin 25: Toxic if swallowed 26: Very Toxic by inhalation 27: Very Toxic in contact with skin 28: Very Toxic if swallowed 29: Contact with water liberates toxic gas 30: Can become highly flammable in use 31: Contact with acids liberates toxic gas 32: Contact with acids liberates very toxic gas 33: Danger of cumulative effects 34: Causes burns

35: Causes severe burns 36: Irritating to the eyes 37: Irritating to the respiratory system 38: Irritating to the skin 39: Danger of very serious irreversible effects 40: Limited evidence of a carcinogenic effect 41: Risk of serious damage to eyes 42: May cause sensitization by inhalation 43: May cause sensitization by skin contact 44: Risk of explosion if heated under confinement 45: May cause cancer 46: May cause heritable genetic damage 48: Danger of serious damage to health by prolonged exposure 49: May cause cancer by inhalation 50: Very Toxic to aquatic organisms 51: Toxic to aquatic organisms 52: Harmful to aquatic organisms 53: May cause long-term adverse effects in the aquatic environment 54: Toxic to flora 55: Toxic to fauna 56: Toxic to soil organisms 57: Toxic to bees 58: May cause long-term adverse effects in the environment 59: Dangerous for the ozone layer 60: May impair fertility 61: May cause harm to the unborn child 62: Possible risk of impaired fertility 63: Possible risk of harm to the unborn child 64: May cause harm to breast-fed babies 65: Harmful: May cause lung damage if swallowed 66: Repeated exposure may cause skin dryness or cracking 67: Vapors may cause drowsiness and dizziness 68: Possible risk of irreversible effects

Risk PhrasesCombination of Particular Risks

14/15: Reacts violently with water, liberating extremely flammable gases 15/29: Contact with water liberates toxic, extremely flammable gas 20/21: Harmful by inhalation and in contact with skin 20/21/22: Harmful by inhalation, in contact with skin and if swallowed 20/22: Harmful by inhalation and if swallowed 21/22: Harmful in contact with skin and if swallowed 23/24: Toxic by inhalation and in contact with skin 23/24/25: Toxic by inhalation, in contact with skin and if swallowed 23/25: Toxic by inhalation and if swallowed 24/25: Toxic in contact with skin and if swallowed 26/27: Very Toxic by inhalation and in contact with skin 26/27/28: Very Toxic by inhalation, in contact with skin and if swallowed 26/28: Very Toxic by inhalation and if swallowed 27/28: Very Toxic in contact with skin and if swallowed 36/37: Irritating to eyes and respiratory system 36/37/38: Irritating to eyes, respiratory system and skin 36/38: Irritating to eyes and skin 37/38: Irritating to respiratory system and skin 39/23: Toxic: danger of very serious irreversible effects through inhalation 39/23/24: Toxic: danger of very serious irreversible effects through inhalation in contact with skin 39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 39/23/25: Toxic: danger of very serious irreversible effects through inhalation and if swallowed 39/24: Toxic: danger of very serious irreversible effects in contact with skin 39/24/25: Toxic: danger of very serious irreversible effects in contact with skin and if swallowed 39/25: Toxic: danger of very serious irreversible effects if swallowed 39/26: Very Toxic: danger of very serious irreversible effects through inhalation 39/26/27: Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin 39/26/27/28: Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 39/26/28: Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed 39/27: Very Toxic: danger of very serious irreversible effects in contact with skin 39/27/28: Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed 39/28: Very Toxic: danger of very serious irreversible effects if swallowed 42/43: May cause sensitization by inhalation and skin contact

48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation 48/20/21: Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin 48/20/21/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed 48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed 48/21: Harmful: danger of serious damage to health by prolonged exposure in contact with skin 48/21/22: Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed 48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed 48/23: Toxic: danger of serious damage to health by prolonged exposure through inhalation 48/23/24: Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin 48/23/24/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed 48/23/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed 48/24: Toxic: danger of serious damage to health by prolonged exposure in contact with skin 48/24/25: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed 48/25: Toxic: danger of serious damage to health by prolonged exposure if swallowed 50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment 68/20: Harmful: possible risk of irreversible effects through inhalation 68/20/21: Harmful: possible risk of irreversible effects through inhalation and in contact with skin 68/20/21/22: Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed 68/20/22: Harmful: possible risk of irreversible effects through inhalation and if swallowed 68/22: Harmful: possible risk of irreversible effects if swallowed 68/21: Harmful: possible risk of irreversible effects in contact with skin 68/21/22: Harmful: possible risk of irreversible effects in contact with skin and if swallowed 68/22: Harmful: possible risk of irreversible effects if swallowed

Safety PhrasesIndication of Safety Precautions

[tr][/tr] S1: Keep locked up 2: Keep out of the reach of children 3: Keep in a cool place 4: Keep away from living quarters 5: Keep contents under ... (appropriate liquid to be specified by the manufacturer) 6: Keep under ... (inert gas to be specified by the manufacturer) 7: Keep container tightly closed 8: Keep container dry 9: Keep container in a well-ventilated place 12: Do not keep the container sealed 13: Keep away from food, drink and animal feeding stuffs 14: Keep away from ... (incompatible materials to be indicated by the manufacturer) 15: Keep away from heat 16: Keep away from sources of ignition - No smoking 17: Keep away from combustible material 18: Handle and open container with care 20: When using, do not eat or drink 21: When using, do not smoke 22: Do not breathe dust 23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) 24: Avoid contact with skin 25: Avoid contact with eyes 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 27: Take off immediately all contaminated clothing 28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 29: Do not empty into drains 30: Never add water to this product 33: Take precautionary measures against static discharges 35: This material and its container must be disposed of in a safe way 36: Wear suitable protective clothing

37: Wear suitable gloves 38: In case of insufficient ventilation, wear suitable respiratory equipment 39: Wear eye/face protection 40: To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer) 41: In case of fire and/or explosion do not breathe fumes 42: During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified) 43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water) 45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 46: If swallowed, seek medical advice immediately and show this container or label 47: Keep at temperature not exceeding ... E C (to be specified by the manufacturer) 48: Keep wetted with ... (appropriate material to be specified by the manufacturer) 49: Keep only in the original container 50: Do not mix with ... (to be specified by the manufacturer) 51: Use only in well-ventilated areas 52: Not recommended for interior use on large surface areas 53: Avoid exposure - obtain special instruction before use 56: Dispose of this material and its container to hazardous or special waste collection point 57: Use appropriate container to avoid environmental contamination 59: Refer to manufacturer/supplier for information on recovery/recycling 60: This material and/or its container must be disposed of as hazardous waste 61: Avoid release to the environment. Refer to special instructions safety data sheet 62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label 63: In case of accident by inhalation, remove casualty to fresh air and keep at rest 64: If swallowed, rinse mouth with water (only if the person is conscious)

Safety PhrasesCombination of Safety Precautions

1/2: Keep locked up and out of the reach of children 3/7: Keep container tightly closed in a cool place 3/9/14: Keep in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer) 3/9/14/49: Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer) 3/9/49: Keep only in the original container in a cool well-ventilated place 3/14: Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer) 7/8: Keep container tightly closed and dry 7/9: Keep container tightly closed and in a well-ventilated place 7/47: Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer) 20/21: When using, do not eat, drink or smoke

24/25: Avoid contact with skin and eyes 27/28: After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer) 29/35: Do not empty into drains, dispose of this container and it's material in a safe way 29/56: Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point 36/37: Wear suitable protective clothing and gloves 36/37/39: Wear suitable protective clothing, gloves and eye/face protection 36/39: Wear suitable protective clothing and eye/face protection 37/39: Wear suitable gloves and eye/face protection 47/49: Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer)

FLUKA BRAND F CODES

F 1 Sensitive to air and humidity. F 2 Sensitive to air and CO2. F 3 Hygroscopic. F 4 Do not heat over …°C.   1 = 10 °C   2 = 20 °C   3 = 30 °C   4 = 40 °C   5 = 50 °C   6 = 60 °C   7 = 70 °C   8 = 80 °C   9 = 90 °C   10 = 100 °C   11 = 110 °C   12 = 120 °C   13 = 130 °C   14 = 140 °C   15 = 150 °C

F 5 Dry material may explode. F 6 Reacts with acids. F 7 Keep under CO2. F 8 Photosensitive. F 9 Keep under nitrogen. F 10 Keep under argon. F 11 Keep under inert gas. F 12 Shake before use. F 13 Malodorous. F 14 Carefully observe warning label. F 15 Limited shelf life. F 16 Decomposes easily. F 17 May decompose by explosion. F 18 Must be handled by instructed people only. F 19 Lachrymator. F 20 Not to be swallowed. F 21 Sensitive to humidity. F 22 Keep dust-free in the dark. F 23 Sensitive to air.

F 24 Spontaneously flammable with alcohol. F 25 Keep under CO. F 26 Before distillation test for absence of peroxides. F 27 Cool before opening. F 28 May become cloudy (Polyformaldehyde). F 29 Spontaneously flammable when dry. F 30 Sediment unavoidable. F 31 Do not puncture. F 32 Avoid contact with heavy metal salts         especially iron salts. F 33 Causes fall in blood pressure. F 34 Sensitive to CO2. F 35 Narcotic effects. F 36 Extremely sensitive to air.

PICTOGRAMS AND HAZARD CODES

	B	Biohazard			F Highly Flammable F+ Extremely Flammable				O	Oxidizing
	C	Corrosive			Xn Harmful Xi Irritant				R	Radioactive
	E	Explosive			N	Dangerous for the environment			T Toxic T+ Very Toxic